Abstract

The article shows how the analysis of limited kinetic data (separate kinetic curves or even parts of them) for the set of sequential reactions with close values of the rate constants of separate stages allows one to get insight into the reaction mechanism, in particular, to find the stage number in which the substance with the constructed kinetic curve is present. The proposed method gives the plausible results when analyzing well-known kinetic curves of hydrocarbon oxidation.

中文翻译：

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线性不可逆顺序反应的反应机理鉴定

摘要

这篇文章展示了对具有不同阶段速率常数接近值的一组连续反应的有限动力学数据（单独的动力学曲线或什至部分）的分析如何使人们深入了解反应机理，特别是，找出具有构造动力学曲线的物质所在的阶段编号。在分析众所周知的烃氧化动力学曲线时，所提出的方法给出了合理的结果。