Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2021-09-24 , DOI: 10.1016/j.cej.2021.132596 Imteaz Ahmed 1 , Zubair Hasan 2 , Gyudong Lee 1 , Hye Jin Lee 1 , Sung Hwa Jhung 1
Removing hazardous organics from water or fuel is important for our clean environment; adsorption over porous materials has been a competitive means to eliminate such organics. Here, the adsorption or removal of hazardous organics with metal-organic framework-based adsorbents was explained, especially adsorption that relies on hydrogen bonding (H-bonding). The bonding details (direction, quantitative contribution, importance of 6-membered rings, and characterizations to support H-bonding) and improved performance via H-bonding were investigated. Finally, prospects for further development or research in the relevant fields were suggested.
中文翻译:
氢键对金属有机骨架材料液相吸附去除有害有机物的贡献
从水或燃料中去除有害有机物对我们的清洁环境很重要;吸附在多孔材料上一直是消除此类有机物的竞争手段。在这里,解释了基于金属-有机骨架的吸附剂对有害有机物的吸附或去除,特别是依赖于氢键(H-键)的吸附。研究了键合细节(方向、定量贡献、6 元环的重要性以及支持 H 键合的特征)和通过 H 键合提高的性能。最后,提出了相关领域进一步发展或研究的前景。