Highly stereo- and enantioselective synthesis of (E)-δ-hydroxymethyl-anti-homoallylic alcohols is reported. Under the developed conditions, reactions between aldehydes and chiral nonracemic α-borylmethyl-(E)-crotylboronate upon oxidative workup gave δ-hydroxymethyl-anti-homoallylic alcohols with high E-selectivities and enantioselectivities.

中文翻译：

---

(E)-δ-羟甲基-抗高烯丙醇通过高度对映选择性和立体选择性醛烯丙基化与 α-Borylmethyl-(E)-巴豆基硼酸酯不对称合成

报道了 ( E ) -δ-羟甲基-抗高烯丙醇的高度立体选择性和对映选择性合成。在所开发的条件下，醛与手性非外消旋 α-硼基甲基-( E )-巴豆基硼酸酯在氧化处理后反应得到具有高E选择性和对映选择性的δ-羟甲基-抗高烯丙醇。