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Gaseous mercury removal using biogenic porous silica modified with potassium bromide
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2021-09-24 , DOI: 10.1016/j.joei.2021.09.004
Dongjing Liu 1 , Lingtao Yang 2 , Bin Li 1 , Jiang Wu 2
Affiliation  

Rice husk, as an abundant agricultural waste and renewable biomass, is adopted to produce porous silica which is used as a potential carbon-free adsorbent for mercury emission control of coal-fired power plants. The rice husk derived porous silica (RHS) exhibits a good Hg0 adsorption capability with Hg0 removal efficiency above 80% in the temperature range of 60–140 °C, which is plausibly due to the big specific surface area and mesoporous structure. The mercury removal performance of RHS can be evidently reinforced by KBr modification. The optimal KBr loading value and reaction temperature are 2 wt% and 140 °C, respectively. Acidic gas components, such as NO and SO2, both show slight inhibitive effects on Hg0 adsorption process probably owing to the competitive adsorption or the elimination of adsorption sites.



中文翻译:

使用溴化钾改性的生物多孔二氧化硅去除气态汞

稻壳作为一种丰富的农业废弃物和可再生生物质,可用于生产多孔二氧化硅,作为潜在的无碳吸附剂,用于控制燃煤电厂的汞排放。稻壳衍生的多孔二氧化硅(RHS)表现出良好的 Hg 0吸附能力,在 60-140 °C 的温度范围内,Hg 0去除效率超过 80%,这可能是由于大的比表面积和介孔结构。KBr改性可以明显增强RHS的除汞性能。最佳 KBr 负载值和反应温度分别为 2 wt% 和 140 °C。酸性气体成分,如 NO 和 SO 2,均对 Hg 0显示出轻微的抑制作用 吸附过程可能是由于竞争吸附或吸附位点的消除。

更新日期:2021-09-24
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