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Unexpected Formation of Metallofulleroids from Multicomponent Reactions, with Crystallographic and Computational Studies of the Cluster Motion
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-09-24 , DOI: 10.1002/anie.202110881
Yanbang Li 1 , Thomas J Emge 1 , Antonio Moreno-Vicente 2 , William P Kopcha 1 , Yue Sun 1 , Iram F Mansoor 1 , Mark C Lipke 1 , Gene S Hall 1 , Josep M Poblet 2 , Antonio Rodríguez-Fortea 2 , Jianyuan Zhang 1
Affiliation  

Various metallofulleroids were generated from a new isocyanide-induced multicomponent reaction on clusterfullerenes. One ketenimine metallofulleroid has fixed Lu3N cluster due to the presence of the nearby organic appendant from a neighbor molecule in the solid state.
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中文翻译:

多组分反应意外形成金属富勒体,以及团簇运动的晶体学和计算研究

各种金属富勒烯是从新的异氰化物诱导的簇富勒烯多组分反应中产生的。由于来自固态相邻分子的附近有机附属物的存在,一种酮烯亚胺金属富勒体具有固定的 Lu 3 N 簇。
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更新日期:2021-11-15
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