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Rotation in an Enantiospecific Self-Assembled Array of Molecular Raffle Wheels
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-09-23 , DOI: 10.1002/anie.202107708
Dennis Meier 1 , Abhishek K Adak 2 , Peter Knecht 1 , Joachim Reichert 1 , Sourav Mondal 2 , Nithin Suryadevara 3 , Senthil Kumar Kuppusamy 4 , Keitaro Eguchi 1 , Matthias K Muntwiler 5 , Francesco Allegretti 1 , Mario Ruben 3, 4, 6 , Johannes V Barth 1 , Shobhana Narasimhan 2 , Anthoula C Papageorgiou 1
Affiliation  

A kagome network on the Ag(111) surface hosts guest molecules with enantiomeric selectivity. Each larger pore confines a single guest molecule. The punctuated pirouette of the guest molecule in this confined space is unravelled by a combination of density functional theory and variable temperature scanning tunnelling microscopy in real time at the single molecule level.
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中文翻译:

对映体特异性自组装分子抽奖轮阵列中的旋转

Ag(111) 表面上的 Kagome 网络承载具有对映体选择性的客体分子。每个较大的孔都限制了一个客体分子。结合密度泛函理论和变温扫描隧道显微镜在单分子水平上实时揭示了客体分子在这个受限空间中的间断旋转。
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更新日期:2021-09-23
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