A simple, convenient procedure for direct transition-metal-free intermolecular chlorodifluoromethylthiolation of a variety of unactivated alkenes and alkynes has been described. This methodology provides a straightforward way to construct a variety of useful SCF₂H-containing chlorides from a wide range of alkenes and alkynes. The developed protocol fulfils the requirements of sustainable and green chemistry.

中文翻译：

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烯烃和炔烃的无过渡金属分子间氯二氟甲基硫醇化

已经描述了一种简单、方便的方法，用于各种未活化的烯烃和炔烃的直接无过渡金属分子间氯二氟甲基硫醇化。这种方法提供了一种直接的方法来从广泛的烯烃和炔烃构建各种有用的含SCF ₂ H 的氯化物。开发的协议满足可持续和绿色化学的要求。