A nickel-catalyzed highly regioselective addition/cyclization of ynamide-benzylnitriles with organoboronic acids has been developed. The reaction offers an attractive route for the construction of diamino-functionalized 1-arylnaphthalenes, which is difficult to synthesize by other methods. In addition, a wide range of functional groups are tolerated in this reaction.

中文翻译：

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炔酰胺-苄腈与有机硼酸的镍催化环化合成邻二氨基官能化 1-芳基萘

已经开发出镍催化的炔酰胺-苄基腈与有机硼酸的高度区域选择性加成/环化。该反应为构建难以通过其他方法合成的二氨基官能化 1-芳基萘提供了一条有吸引力的途径。此外，在该反应中可以容忍范围广泛的官能团。