Journal of Nuclear Materials ( IF 3.1 ) Pub Date : 2021-09-23 , DOI: 10.1016/j.jnucmat.2021.153310 Song Zeng 1 , Junhua Tian 1 , Xiaochun Han 1 , Yan Meng 1 , Ming Zhu 2 , Haibin Zhang 1
In this study, the compact and uniform CrSi (Cr0.92Si0.08, Cr0.85Si0.15, Cr0.65Si0.35) coatings have been deposited on zircaloy-4 substrates by magnetron sputtering technique, and their oxidation performances in steam environment have been investigated at 1200°C for 60 min. Microstructures and phase compositions of coatings before and after oxidation indicate that CrSi coatings exhibit protective behavior. The dense Cr2O3 oxide layer on CrSi coatings can significantly improve the oxidation resistance, and their weight gains are reduced. The Cr0.92Si0.08 coating shows the optimum performance due to the integrality and protectiveness of the Cr2O3 oxide layer.
中文翻译:
Zry-4基体上CrSi涂层在1200℃蒸汽环境中的氧化行为
在这项研究中,通过磁控溅射技术在 zircaloy-4 基体上沉积了致密均匀的 CrSi(Cr 0.92 Si 0.08,Cr 0.85 Si 0.15,Cr 0.65 Si 0.35)涂层,并研究了它们在蒸汽环境中的氧化性能1200°C 60 分钟。氧化前后涂层的微观结构和相组成表明 CrSi 涂层表现出保护行为。CrSi涂层上致密的Cr 2 O 3氧化层可显着提高抗氧化性,并减少其增重。Cr 0.92 Si 0.08由于 Cr 2 O 3氧化物层的完整性和保护性,涂层显示出最佳性能。