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Enantioselective Synthesis of the Sex Pheromone of Lichen Moth, Miltochrista calamine, and Its Diastereomer
Synlett ( IF 2 ) Pub Date : 2021-09-22 , DOI: 10.1055/s-0040-1719835
Jiangchun Zhong , Gucheng Yuan , Jiawei Liu , Shihang Yu , Xueyang Wang , Qinghua Bian , Min Wang

The synthesis of a Miltochrista calamine sex pheromone and its diastereomer has been developed. The key steps of the synthetic approach involved Evans’ chiral auxiliaries and the addition of alkyne to aldehyde, which were firstly applied to prepare this sex pheromone and its diastereomer. The synthetic sex pheromone could be used to trap insects and study physiological and ecological questions of the lichen moth.



中文翻译:

地衣蛾性信息素、Miltochrista炉甘石及其非对映体的对映选择性合成

已经开发了Miltochrista 炉甘石性信息素及其非对映异构体的合成。合成方法的关键步骤涉及 Evans 的手性助剂和炔与醛的加成,这些步骤首先用于制备这种性信息素及其非对映异构体。合成性信息素可用于诱捕昆虫和研究地衣蛾的生理和生态问题。

更新日期:2021-09-23
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