3,3′-((phenylmethylene)bis(4-methoxy-3,1-phenylene))dipyridine L was used as a novel N,N-bidentate triarylmethane-based ligand in Mizoroki-Heck reactions. This air and moisture stable ligand was identified as a useful alternative to the commonly used phosphine ligands. The in-situ generated complex of L with Cu(OAc)₂ showed excellent activity in cross coupling of aldehydes with olefins and a selected library of formylated olefins was prepared in high yields. The Friedel-Crafts alkylation of arenes with the derived olefins catalyzed by Fe(OTs)₃ was also employed for the preparation of functionalized triarylmethanes. This alternative method offers several important advantages including mild reaction conditions, short reaction times, high yields, simple work-up procedure, and broad substrate scope.

中文翻译：

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使用新型 N,N-二齿 TRAM 基配体铜催化烯烃芳基化：在功能化三芳基甲烷合成中的应用[]**

3,3'-((苯基亚甲基)双(4-甲氧基-3,1-亚苯基))二吡啶L在Mizoroki-Heck反应中用作新型N,N-二齿三芳基甲烷基配体。这种对空气和水分稳定的配体被确定为常用膦配体的有用替代品。L 与 Cu(OAc) ₂的原位生成复合物在醛与烯烃的交叉偶联中表现出优异的活性，并且以高产率制备了选定的甲酰化烯烃库。Fe(OTs) ₃催化芳烃与衍生烯烃的 Friedel-Crafts 烷基化也用于制备官能化的三芳基甲烷。这种替代方法提供了几个重要的优点，包括反应条件温和、反应时间短、收率高、后处理程序简单和底物范围广。