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Potential of Molecular Nitrogen Fixation by Carbonyl Clusters of Platinum Metals in Lower Oxidation States: A Review
Russian Journal of Inorganic Chemistry ( IF 2.1 ) Pub Date : 2021-09-21 , DOI: 10.1134/s0036023621090023
I. V. Fedoseev 1 , V. V. Vasekin 1 , A. V. Shevelkov 2
Affiliation  

Abstract

This minireview presents the results that show the potential of molecular nitrogen fixation by carbonyl cluster compounds of platinum metals at room temperature and atmospheric pressure to produce ammonia or its derivatives. Although the main attention is given to processes with the participation of derivatives of platinum and palladium, it was demonstrated that molecular nitrogen fixation is characteristic of all the platinum metals, except osmium.



中文翻译:

铂金属羰基簇在较低氧化状态下固定分子氮的潜力:综述

摘要

该小型综述的结果表明,铂金属的羰基簇化合物在室温和大气压下具有分子固氮的潜力,以产生氨或其衍生物。尽管主要关注铂和钯衍生物参与的过程,但已证明分子固氮是除锇以外的所有铂金属的特征。

更新日期:2021-09-22
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