Great progress has been made in the tandem annulation of enynes in the past few years. This review only presents the corresponding reactions of 1,3-enyne structural motifs to provide the functionalized pyridine and pyrrole derivatives. The functionalization reactions cover iodination, bromination, trifluoromethylation, azidation, carbonylation, arylation, alkylation, selenylation, sulfenylation, amidation, esterification, and hydroxylation. We also briefly introduce the applications of the products and the reaction mechanisms for the synthesis of corresponding N-heterocycles.

中文翻译：

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1,3-烯炔与官能化吡啶和吡咯衍生物串联环化的最新进展

在过去几年中，烯炔的串联环化取得了很大进展。本综述仅介绍了 1,3-烯炔结构基序的相应反应，以提供功能化的吡啶和吡咯衍生物。功能化反应包括碘化、溴化、三氟甲基化、叠氮化、羰基化、芳基化、烷基化、硒化、磺化、酰胺化、酯化和羟基化。我们还简要介绍了产物的应用和合成相应N-杂环的反应机理。