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Ozonolysis of α-angelica lactone: a renewable route to malonates
Chemical Communications ( IF 4.9 ) Pub Date : 2021-09-13 , DOI: 10.1039/d1cc03820f Andrea Dell'Acqua 1 , Lukas Wille 1 , Bernhard M Stadler 1 , Sergey Tin 1 , Johannes G de Vries 1
Chemical Communications ( IF 4.9 ) Pub Date : 2021-09-13 , DOI: 10.1039/d1cc03820f Andrea Dell'Acqua 1 , Lukas Wille 1 , Bernhard M Stadler 1 , Sergey Tin 1 , Johannes G de Vries 1
Affiliation
Industrially relevant intermediates such as malonic acid, malonates and 3-oxopropionates can be easily accessed by ozonolysis of α-angelica lactone, derived from the platform chemical levulinic acid. The roles of the solvent and of the quenching conditions are of key importance for the outcome of the reaction.
中文翻译:
α-当归内酯的臭氧分解:丙二酸的可再生途径
工业相关的中间体,如丙二酸、丙二酸酯和 3-氧代丙酸酯,可以通过臭氧分解来自平台化学乙酰丙酸的 α-当归内酯轻松获得。溶剂和淬灭条件的作用对反应的结果至关重要。
更新日期:2021-09-22
中文翻译:
α-当归内酯的臭氧分解:丙二酸的可再生途径
工业相关的中间体,如丙二酸、丙二酸酯和 3-氧代丙酸酯,可以通过臭氧分解来自平台化学乙酰丙酸的 α-当归内酯轻松获得。溶剂和淬灭条件的作用对反应的结果至关重要。