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Scintillation characteristics and temperature quenching of radio- and photoluminescence of Mg2+-codoped (Lu,Gd)3Al2.4Ga2.6O12:Ce garnet crystals
Optical Materials ( IF 3.9 ) Pub Date : 2021-09-21 , DOI: 10.1016/j.optmat.2021.111595
Warut Chewpraditkul 1 , Nakarin Pattanaboonmee 1 , Ongsa Sakthong 1 , Weerapong Chewpraditkul 1 , Akihiro Yamaji 2 , Shunsuke Kurosawa 3 , Kei Kamada 3 , Akira Yoshikawa 2, 3 , Michał Makowski 4 , Marcin E. Witkowski 4 , Winicjusz Drozdowski 4 , Alena Beitlerova 5 , Romana Kucerkova 5 , Vladimir Babin 5 , Martin Nikl 5
Affiliation  

Luminescence and scintillation characteristics of Mg2+-codoped (LuxGd3-x)Al2.4Ga2.6O12:Ce (x = 0.2–0.8) garnet crystals grown by the micro-pulling down method are investigated. The Ce3+ 5d1 → 4f luminescence is blue-shifted with increasing Lu content due to the decrease in crystal field splitting of the 5 d levels. With increasing Lu content, the shortening of scintillation decay time accompanied with a decrease of LY value as measured at room temperature can be explained by thermal ionization of the Ce3+ 5d1 excited state. Co-doping with Mg2+ results in the shortening of scintillation decay time, the reduction of LY value and afterglow intensity. At low temperature the radioluminescence quenching is observed in correlation with large thermoluminescence peaks, which can be attributed to the localization of electrons at intrinsic shallow traps.



中文翻译:

Mg2+共掺杂(Lu,Gd)3Al2.4Ga2.6O12:Ce石榴石晶体的辐射和光致发光闪烁特性和温度猝灭

研究了通过微下拉法生长的 Mg 2+共掺杂 (Lu x Gd 3-x )Al 2.4 Ga 2.6 O 12 :Ce (x = 0.2–0.8) 石榴石晶体的发光和闪烁特性。由于 5 d 能级的晶场分裂减少,Ce 3+ 5d 1 → 4f 发光随着 Lu 含量的增加而发生蓝移。随着Lu含量的增加,闪烁衰减时间的缩短伴随着室温下LY值的降低可以通过Ce 3+ 5d 1激发态的热电离来解释。与 Mg 2+共掺杂导致闪烁衰减时间缩短,LY值和余辉强度降低。在低温下,观察到与大热释光峰相关的辐射发光猝灭,这可归因于电子在本征浅陷阱处的定位。

更新日期:2021-09-21
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