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Impact of piezoelectric effect on the heterogeneous visible photocatalysis of g-C3N4/Ag/ZnO tricomponent
Chemosphere ( IF 8.8 ) Pub Date : 2021-09-21 , DOI: 10.1016/j.chemosphere.2021.132298
Pavan P Gotipamul 1 , Ganesh Vattikondala 1 , Karthik Dilly Rajan 1 , Shweta Khanna 1 , Maheswaran Rathinam 1 , Siva Chidambaram 1
Affiliation  

In recent years, the piezophotocatalytic mechanism had been intensively recognized as a potential and promising route to sewage treatment. Here we report the piezoelectric effect improved heterogeneous photocatalysis of g-C3N4/Ag/ZnO (g-CN/A/Z) tricomponent in rhodomine B (RhB) degradation. Initially, the nanomaterials were characterized for their physico-chemical and optoelectronic properties using analytical techniques such as x-ray diffraction (XRD), scanning & transmission electron microscopes (SEM & TEM), UV–vis spectrophotometer and photoluminescence spectroscopy (PL). In addition, the photoelectrochemical activity of determining the photocurrent density and electrochemical impendence response were also been conducted. The catalytic properties of the tricomponent, g-CN/A/Z was studied with the degradation of RhB with visible photons irradiation and ultrasonication. In piezophotocatalysis, degradation up to 89% of RhB was achieved with 1.26 folds synergetic effect on par to the photocatalysis and piezocatalysis.



中文翻译:

压电效应对g-C3N4/Ag/ZnO三组分异相可见光催化的影响

近年来,压电光催化机理被广泛认为是一种潜在的、有前景的污水处理途径。在这里,我们报告了 gC 3 N 4的压电效应改进的多相光催化/Ag/ZnO (g-CN/A/Z) 三组分降解罗多明 B (RhB)。最初,使用分析技术如 X 射线衍射 (XRD)、扫描和透射电子显微镜 (SEM & TEM)、紫外-可见分光光度计和光致发光光谱 (PL) 对纳米材料的物理化学和光电特性进行了表征。此外,还进行了测定光电流密度和电化学阻抗响应的光电化学活性。研究了三组分 g-CN/A/Z 的催化性能,通过可见光子照射和超声处理降解 RhB。在压电光催化中,RhB 的降解率高达 89%,与光催化和压电催化相比,协同效应提高了 1.26 倍。

更新日期:2021-10-02
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