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Visible-Light-Driven Dehydrogenative Coupling of Primary Alcohols with Phenols Forming Aryl Carboxylates
Organic Letters ( IF 5.2 ) Pub Date : 2021-09-20 , DOI: 10.1021/acs.orglett.1c03017
Tairin Kawasaki 1 , Tomohiro Tosaki 1 , Naoki Ishida 1 , Masahiro Murakami 1
Affiliation  

A preparative method for obtaining aryl esters from aliphatic primary alcohols and phenols was developed. The reaction proceeds under the irradiation of visible light at ambient temperature, dispensing with any oxidant or hydrogen acceptor. Primary alcohols having a variety of functional groups are successfully esterified with phenols. The produced esters can be utilized as the precursor of various carbonyl compounds.

中文翻译:

伯醇与酚的可见光驱动脱氢偶联形成芳基羧酸酯

开发了一种从脂肪族伯醇和酚类中获得芳基酯的制备方法。该反应在环境温度下在可见光照射下进行,无需任何氧化剂或氢受体。具有多种官能团的伯醇成功地与酚类酯化。生成的酯可用作各种羰基化合物的前体。
更新日期:2021-10-01
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