A series of Sr₃AlO₄F:Sm³⁺, La³⁺, Li⁺ orange-red-emitting phosphors were synthesized via a solid-state reaction with charge compensator Li⁺ co-doping for luminescence enhancement. The X-ray diffraction results demonstrated that all samples were consistent with standard Sr₃AlO₄F structure belonging to tetragonal phase with I4/mcm space group. The effects of La³⁺ co-doping and Li⁺ co-doping on the structure and luminescence properties of Sr₃AlO₄F:Sm³⁺ were investigated. The emission spectrum of Sm³⁺-doped phosphors was composed of several emission peaks at 565 nm (⁴G_5/2→⁶H_5/2), 602 nm (⁴G_5/2→⁶H_7/2) and 650 nm (⁴G_5/2→⁶H_9/2), respectively. After co-doping La³⁺, the luminescence intensity of Sr₃AlO₄F:Sm³⁺, La³⁺ sample was elevated to 1.46 times of that of Sr₃AlO₄F:Sm³⁺ phosphor, which is in consequence of the environmental effect of crystal field around luminescence center. Furthermore, depend on charge compensation effect, the luminescence intensity of Sr₃AlO₄F:Sm³⁺, La³⁺, Li⁺ phosphor was further enhanced by 1.48 times higher than that of Sr₃AlO₄F:Sm³⁺, La³⁺ phosphor. A w-LEDs device was packaged via coating the as-prepared phosphor on n-UV chip of 395 nm with commercial phosphors. These results indicated that there is a potential application for Sr₃AlO₄F:Sm³⁺, La³⁺, Li⁺ phosphor as orange-red component in w-LEDs.

通过与电荷补偿剂Li ⁺共掺杂的固态反应合成了一系列Sr ₃ AlO ₄ F:Sm ³⁺、La ³⁺、Li ⁺橙红色荧光粉，以增强发光。X射线衍射结果表明，所有样品均符合标准的Sr ₃ AlO ₄ F结构，属于四方相I 4 /mcm空间群。La ³⁺共掺杂和Li ⁺共掺杂对Sr ₃ AlO ₄ F:Sm ³⁺结构和发光性能的影响被调查。Sm ³⁺掺杂荧光粉的发射光谱由565 nm ( ⁴ G _5/2 → ⁶ H _5/2 )、602 nm ( ⁴ G _5/2 → ⁶ H _7/2 ) 和650 nm 处的几个发射峰组成。nm ( ⁴ G _5/2 → ⁶ H _9/2 )，分别。共掺杂La ^{3+ 后}，Sr ₃ AlO ₄ F:Sm ³⁺ , La ³⁺样品的发光强度提高到Sr ₃ AlO ₄ F:Sm的1.46倍³⁺荧光粉，这是发光中心周围晶体场环境效应的结果。此外，依赖于电荷补偿的效果，Sr的发光强度₃的AlO ₄ F：钐³⁺，拉³⁺，李⁺荧光体进一步通过1.48倍增强比Sr中更高₃的AlO ₄ F：钐³⁺，拉³⁺磷。甲瓦特-LEDs设备经涂覆上的商业荧光395nm的正UV芯片所制备的磷光体封装。这些结果表明 Sr ₃ AlO ₄ F:Sm ³⁺有潜在的应用, La ³⁺ , Li ⁺荧光粉作为w -LED 中的橙红色成分。