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Structurally improved Li4SiO4 sorbents derived from lithium salicylate precursor for enhanced CO2 capture
Fuel Processing Technology ( IF 7.5 ) Pub Date : 2021-09-20 , DOI: 10.1016/j.fuproc.2021.107027
Yingchao Hu 1, 2 , Lei Liu 1 , Wenqiang Liu 1 , Zijian Zhou 1
Affiliation  

Li4SiO4 sorbents have exhibited promising prospects for high-temperature CO2 capture. However, conventional Li4SiO4 using solid-state reaction method usually exhibits dense structures with barren porosity, limiting the CO2 sorption. To solve this problem, a sol-mixing method using organometallic lithium precursors was employed to produce ‘new’ Li4SiO4 sorbents with improved CO2 sorption performance. The obtained Li4SiO4 from lithium salicylate precursor exhibited enhanced specific surface area and modified micromorphology compared to the conventional Li4SiO4. The morphology showed that the ‘new’ Li4SiO4 possessed many fluff-like folds on the surface, in comparison with the smooth surfaces of conventional sorbent. As a result, the ‘new’ sorbent exhibited CO2 uptake of ~0.15 g/g, which is more than three times as high as that of the conventional one. Furthermore, the CO2 uptake was further enhanced to 0.32 g/g by K2CO3 doping. After granulation, the pellets also presented good CO2 sorption performance as well as excellent mechanical strength for practical applications. Generally, the good sorption performance and excellent mechanical strength demonstrated the effectiveness of sol-mixing method and lithium salicylate as precursors for the production of efficient Li4SiO4 sorbents.



中文翻译:

来自水杨酸锂前驱体的结构改进的 Li4SiO4 吸附剂,用于增强 CO2 捕获

Li 4 SiO 4吸附剂在高温CO 2捕获方面表现出良好的前景。然而,使用固态反应方法的常规Li 4 SiO 4通常表现出致密的结构和贫瘠的孔隙率,限制了CO 2 的吸附。为了解决这个问题,使用有机金属锂前体的溶胶混合方法被用来生产具有改进的 CO 2吸附性能的“新”Li 4 SiO 4吸附剂。与传统的锂相比,从水杨酸锂前驱体中获得的 Li 4 SiO 4表现出更高的比表面积和改进的微观形态。4 SiO 4。形态表明,与传统吸附剂的光滑表面相比,“新”Li 4 SiO 4 表面具有许多绒毛状褶皱。因此,“新”吸附剂的 CO 2吸收量为~0.15 g/g,是传统吸附剂的三倍多。此外,通过K 2 CO 3掺杂,CO 2吸收进一步提高至0.32 g/g 。造粒后,粒料也呈现出良好的 CO 2吸附性能以及实际应用中优异的机械强度。一般来说,良好的吸附性能和优异的机械强度证明了溶胶混合法和水杨酸锂作为生产高效 Li 4 SiO 4吸附剂的前驱体的有效性。

更新日期:2021-09-20
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