This paper aims to provide a detailed review of the fundamentals and applications of mechanical Raman spectroscopy in the field of energetic materials. Firstly, the principle behind mechanical Raman spectroscopy (MRS) is introduced to measure stress and temperature in a material. Afterward, the use of MRS to obtain microscale properties in an energetic material microstructure is discussed for quasi-static loading and dynamic loading experiments. Thereafter, the measurement of cohesive law parameters for interface separation in energetic material is explained. Finally, quantification of thermal conductivity at the interface level is presented. Later, the mechanism of obtaining time-resolved Raman spectra for the analysis of shock wave propagation in energetic material is explained. This work presents a comprehensive view of the existing applications of MRS as well as possible enhancements to the use of Raman spectroscopy to understand the behavior of complex energetic microstructures.

本文旨在详细回顾机械拉曼光谱在含能材料领域的基础知识和应用。首先，介绍了机械拉曼光谱 (MRS) 背后的原理来测量材料中的应力和温度。然后，讨论了在准静态加载和动态加载实验中使用 MRS 在含能材料微观结构中获得微观特性。此后，解释了含能材料界面分离的内聚定律参数的测量。最后，介绍了界面级热导率的量化。随后，解释了获得时间分辨拉曼光谱以分析高能材料中激波传播的机制。