当前位置: X-MOL 学术Appl. Phys. A › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Magnetic and microwave absorption properties of La3+-substituted manganese ferrites synthesized via solid-state reaction method
Applied Physics A ( IF 2.7 ) Pub Date : 2021-09-15 , DOI: 10.1007/s00339-021-04907-w
Yunasfi 1 , Ade Mulyawan 1 , Mashadi 1 , Didin S. Winatapura 1 , A. A. Wisnu 1
Affiliation  

La3+-substituted manganese ferrites with chemical formula MnLaxFe(2−x)O4 (0 ≤ x ≤ 0.03) were prepared via solid -state reaction method. X-ray diffraction (XRD) analysis with Rietveld refinement method confirmed that all compositions exhibited a single-phase formation of manganese ferrite (MnFe2O4, cubic (Fd−3 m)). The lattice parameters were found to decrease with increasing La3+ ion substitution from 8.505 Å (x = 0) to 8.485 Å (x = 0.03). The substitution process was found to induce the lattice strain and hinder the crystallite growth in the La3+-doped samples. The particle size distribution curve of the La3+-substituted samples was shifted to smaller size compared to the original sample. Magnetic properties measurement was carried out to reveal the magnetic parameters such as saturation magnetization (Ms), remanence magnetization (Mr), and field coercivity (Hc). The Ms was determined from the law of approach to saturation (LAS) method. As the results, we found that the Ms values were decreased from 17.56 emu/g (x = 0) to 7.09 emu/g (x = 0.03), while the Hc values were increased from 126.50 Oe (x = 0) to 202.00 Oe (x = 0.03). The microwave absorbing property of all MnLaxFe(2−x)O4 (x = 0.0; 0.01; 0.02 and 0.03) series was measured in X-band frequency range (8–12 GHz). The results showed that the substitution of La3+ ion was responsible to the improvement of the microwave absorbing ability with the attenuation of microwave which was increased from 91.57 to 97.61%. Thus, the composition with x = 0.03 (MnLa0.03Fe1.97O4) showed an excellent response and can be considered as microwave absorbing material candidate.



中文翻译:

固相反应合成La3+-取代锰铁氧体的磁吸波特性

 通过固相反应方法制备了化学式为MnLa x Fe (2- x ) O 4 (0 ≤  x ≤ 0.03)的La 3+取代的锰铁氧体。使用 Rietveld 精修方法的 X 射线衍射 (XRD) 分析证实,所有组合物都显示出锰铁氧体 (MnFe 2 O 4,立方 ( Fd - 3 m ))的单相形成。发现晶格参数随着 La 3+离子取代度从 8.505 Å ( x  = 0) 增加到 8.485 Å ( x = 0.03)。发现置换过程会引起晶格应变并阻碍 La 3+掺杂样品中的微晶生长。与原始样品相比,La 3+取代样品的粒度分布曲线移动到更小的尺寸。进行磁特性测量以揭示磁参数,如饱和磁化强度 ( M s )、剩磁 ( M r ) 和磁场矫顽力 ( H c )。的中号小号从的方法法律来饱和(LAS)方法确定。作为结果,我们发现M s值从 17.56 emu / g (x  = 0) 到 7.09 emu / g ( x  = 0.03),而H c值从 126.50 Oe ( x  = 0)增加到 202.00 Oe ( x  = 0.03)。 在 X 波段频率范围 (8-12 GHz) 中测量了所有 MnLa x Fe (2- x ) O 4 ( x = 0.0;0.01;0.02 和 0.03) 系列的微波吸收性能。结果表明,La 3+离子的取代是提高微波吸收能力的原因,微波的衰减从91.57%增加到97.61%。因此,x  = 0.03 (MnLa 0.03 Fe1.97 O 4 ) 表现出极好的响应,可以被认为是微波吸收材料的候选者。

更新日期:2021-09-16
down
wechat
bug