Policies such as the Air Pollution Prevention and Control Action Plan have been implemented in Beijing to address acid rain pollution. In this study, we evaluate the effects of these policies by analyzing rainfall monitoring data from 1997 to 2020, acidification characteristics, and chemical components of precipitation in Beijing. We found that precipitation pH values had significantly changed in 2008, showing an overall declining trend during 1997–2008 before gradually recovering. The frequency of acid rain was first increased and then decreased, reaching zero levels after 2017. The multi-year average pH in urban (1997–2020), suburban (1997–2020), and background (2004–2020) sites was 5.74 ± 0.67 Â, 6.53 ± 0.54 Â, and 6.49 ± 0.64 Â, respectively. The predominant cations in precipitation were NH₄⁺ and Ca²⁺, where Ca²⁺ concentrations dropped from 332.1 μeq·L⁻¹ in 1997 to 179.3 μeq·L⁻¹ by 2015 and 81.39 μeq·L⁻¹ by 2020. In contrast, NH₄⁺ concentrations were first increased from 193.4 μeq·L⁻¹ in 1997 to 270.5 μeq·L⁻¹ in 2015 and then decreased to 206.78 μeq·L⁻¹ by 2020. The concentration of the predominant anions, SO₄²⁻ and NO₃⁻, was generally decreased; SO₄²⁻ concentration was decreased from 350.88 μeq·L⁻¹ in 1999 to 88.19 μeq·L⁻¹ in 2020. However, NO₃⁻ underwent a down-up-down trend, dropping slowly from 125.3 μeq·L⁻¹ in 1997 to 52.2 μeq·L⁻¹ in 2004, then significantly increasing to 173.06 μeq·L⁻¹ in 2014 before showing a downward trend in volatility. The [SO₄²⁻]:[NO₃⁻] ratio was gradually decreased from 3.3 in 1997 to 1.5 in 2015, then dropped to 0.9 in 2020, indicating that the type of precipitation gradually shifted from a predominantly sulfuric acid type to a more mixed type. Conversely, the [Ca²⁺]:[NH₄⁺] ratio showed a decreasing trend, suggesting NH₄⁺ as the principal neutralizing agent in recent years. The correlation coefficients among the major crustal source components (Ca²⁺, K⁺, and Mg²⁺) were relatively high in the precipitation, suggesting that the contribution from ground dust was significant. The major acidic anions were primarily attributed to human activities.