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Corrosion characteristics of T91 steel in lead–bismuth eutectic with different oxygen concentrations at 500°C
Materials and Corrosion ( IF 1.8 ) Pub Date : 2021-09-14 , DOI: 10.1002/maco.202112505
Shujian Tian 1 , Yongqiang Pang 1 , Zhizhong Jiang 2 , Lin Luo 2 , Zunqi Xiao 2
Affiliation  

Corrosion tests of T91 were carried out in the stagnant lead–bismuth eutectic (LBE) containing 10−6, 10−7, and 10−8 wt% oxygen at 500°C for up to 2000 h, respectively. The dependence of corrosion characteristics on oxygen concentrations in LBE was obtained. The results show that the oxide-scale structure changes from a three-layer magnetite/spinel/internal oxidation zone (IOZ) scale under the oxygen concentration of 10−6 wt%, to the formation of a two-layer spinel/IOZ scale under the oxygen concentrations of 10−7 and 10−8 wt%. In addition, with the decrease of the oxygen concentration, the Cr/Fe ratio in the Fe–Cr spinel slightly increases in a linear rule while the thicknesses of the oxide layers gradually decrease.

中文翻译:

T91钢在500℃不同氧浓度铅铋共晶腐蚀特性

T91 的腐蚀测试分别在含有 10 -6、10 -7和 10 -8  wt% 氧的停滞铅铋共晶 (LBE) 中进行,时间分别为 2000 小时。获得了腐蚀特性对 LBE 中氧浓度的依赖性。结果表明,在氧浓度为 10 -6  wt% 时,氧化皮结构从三层磁铁矿/尖晶石/内部氧化带 (IOZ) 氧化皮转变为在氧浓度为 10 -6 wt% 时形成的两层尖晶石/IOZ 氧化皮。 10 -7和 10 -8的氧浓度 重量%。此外,随着氧浓度的降低,Fe-Cr 尖晶石中的 Cr/Fe 比值呈线性增加,而氧化层的厚度逐渐减小。
更新日期:2021-09-14
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