Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π-Conjugated Phosphate,Angewandte Chemie International Edition

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Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π-Conjugated Phosphate
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-09-15 , DOI: 10.1002/anie.202111604
Jingyu Guo _{1,

2} , Abudukadi Tudi _{1,

2} , Shujuan Han _{1,

2} , Zhihua Yang _{1,

2} , Shilie Pan _{1,

2}

Affiliation

Sn₂PO₄I and Sn₂BO₃I are designed and synthesized successfully based on the unique two-dimensional layered structure in KBe₂BO₃F₂ (KBBF), in which the birefringence of Sn₂PO₄I is the largest among the reported borates and phosphates.