当前位置: X-MOL 学术Front. Environ. Sci. Eng. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions
Frontiers of Environmental Science & Engineering ( IF 6.4 ) Pub Date : 2021-09-08 , DOI: 10.1007/s11783-021-1437-z
Xianying Ma 1, 2 , Xinhui Zhou 1, 2 , Mengjie Zhao 1, 2 , Wenzhuo Deng 1, 2 , Yanxiao Cao 1, 2 , Jingcheng Zhou 1, 2 , Junfeng Wu 3
Affiliation  

Microplastics (MPs) are widely present in a variety of environmental media and have attracted more and more attention worldwide. However, the effect of MPs on the interaction between heavy metals and soil, especially in soil solid fraction level, is not well understood. In this study, batch experiments were performed to investigate the adsorption characteristics of Cd in bulk soil and three soil solid fractions (i.e. particulate organo matter (POM), organic-mineral compounds (OMC), and mineral) with or without polypropylene (PP) MPs. The results showed that the addition of PP-MPs reduced the Cd adsorption capacity of the bulk soil in aqueous solution, and the effects varied with PP-MPs dose and aging degree. Whereas, the responses of the three fractions to PP-MPs were different. In presence of PP-MPs, the POM and OMC fractions showed negative adsorption effects, while the mineral fraction showed positive adsorption. For the bulk soil, POM and OMC fractions, the adsorption isotherm fitted to the Langmuir model better than the Freundlich model, whereas, the Freundlich isotherm model was more fitted for the mineral fraction. Combined with the comprehensive analysis of the partitioning coefficients, XRD and FTIR results, it was found that OMC fraction extremely likely play a leading role in the bulk soil adsorption of Cd in this study. Overall, the effect of MPs on adsorption capacity of the bulk soil for Cd may be determined by the proportion of POM, OMC, and mineral fractions in the soil, but further confirmation is needed.



中文翻译:

聚丙烯微塑料改变不同土壤固体组分对镉的吸附能力

微塑料(MPs)广泛存在于各种环境介质中,并在世界范围内引起越来越多的关注。然而,MPs对重金属与土壤相互作用的影响,尤其是在土壤固体成分水平上的影响尚不清楚。在这项研究中,进行批量实验以研究 Cd 在散装土壤和三种土壤固体部分(即颗粒有机物 (POM)、有机矿物化合物 (OMC) 和矿物)中的吸附特性,有或没有聚丙烯 (PP)议员。结果表明,PP-MPs的添加降低了大块土壤在水溶液中对Cd的吸附能力,且影响随PP-MPs用量和老化程度而变化。然而,三个部分对 PP-MP 的反应是不同的。在 PP-MP 存在的情况下,POM 和 OMC 部分表现出负吸附作用,而矿物部分表现出正吸附作用。对于大块土壤、POM 和 OMC 部分,Langmuir 模型的吸附等温线比 Freundlich 模型更适合,而 Freundlich 等温线模型更适合矿物部分。结合分配系数、XRD 和 FTIR 结果的综合分析,发现 OMC 部分极有可能在本研究中对土壤大量吸附 Cd 起主导作用。总体而言,MPs 对大块土壤对 Cd 吸附能力的影响可能取决于土壤中 POM、OMC 和矿物质部分的比例,但需要进一步确认。Langmuir 模型的吸附等温线比 Freundlich 模型更适合,而 Freundlich 等温线模型更适合矿物部分。结合分配系数、XRD 和 FTIR 结果的综合分析,发现 OMC 部分极有可能在本研究中对土壤大量吸附 Cd 起主导作用。总体而言,MPs 对大块土壤对 Cd 吸附能力的影响可能取决于土壤中 POM、OMC 和矿物质部分的比例,但需要进一步确认。Langmuir 模型的吸附等温线比 Freundlich 模型更适合,而 Freundlich 等温线模型更适合矿物部分。结合分配系数、XRD 和 FTIR 结果的综合分析,发现 OMC 部分极有可能在本研究中对土壤大量吸附 Cd 起主导作用。总体而言,MPs 对大块土壤对 Cd 吸附能力的影响可能取决于土壤中 POM、OMC 和矿物质部分的比例,但需要进一步确认。结果表明,在本研究中,OMC 部分极有可能在土壤对 Cd 的大量吸附中起主导作用。总体而言,MPs 对大块土壤对 Cd 吸附能力的影响可能取决于土壤中 POM、OMC 和矿物质部分的比例,但需要进一步确认。结果表明,在本研究中,OMC 部分极有可能在土壤对 Cd 的大量吸附中起主导作用。总体而言,MPs 对大块土壤对 Cd 吸附能力的影响可能取决于土壤中 POM、OMC 和矿物质部分的比例,但需要进一步确认。

更新日期:2021-09-15
down
wechat
bug