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Thermodynamics of Solid and Liquid MnS–CrS–FeS Phase in Equilibrium with Molten Fe–Cr–Mn–S Alloy
ISIJ International ( IF 1.8 ) Pub Date : 2021-09-15 , DOI: 10.2355/isijinternational.isijint-2021-088
Yan Lu 1 , Takahiro Miki 1
Affiliation  

Thermodynamic property of solid MnS–CrS–FeS system was determined based on the combination between thermodynamic properties of liquid MnS–FeS, CrS–FeS, and MnS–CrS–FeS phase determined by the authors and reported phase diagram of MnS–FeS, CrS–FeS and MnS–CrS system. The determined parameters were verified by comparison with experimental results of equilibrium relationship between metal/sulfide in Fe–Cr–Mn–S system at 1793 K. By utilizing the determined parameters, phase equilibria involving sulfide phase in liquid Fe–Cr–Mn–S system was established. According to the phase equilibria information, controllability of MnS–CrS–FeS sulfide phase in typical stainless steel during solidification was evaluated.



中文翻译:

与熔融 Fe-Cr-Mn-S 合金平衡的固态和液态 MnS-CrS-FeS 相的热力学

固体 MnS-CrS-FeS 体系的热力学性质是根据​​作者确定的液态 MnS-FeS、CrS-FeS 和 MnS-CrS-FeS 相的热力学性质和报告的 MnS-FeS、CrS 相图的组合来确定的–FeS 和 MnS–CrS 系统。通过与 1793 K Fe-Cr-Mn-S 体系中金属/硫化物平衡关系的实验结果对比验证了确定的参数。制度成立。根据相平衡信息,评估了典型不锈钢在凝固过程中 MnS-CrS-FeS 硫化物相的可控性。

更新日期:2021-09-15
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