Van der Waals organic/inorganic heterostructures in the two-dimensional (2D) limit with extensive structural tunability will advance the development of artificial solids with tailored functionalities. Recent breakthroughs in several types of 2D organic materials, including molecular monolayer films, 2D polymers, covalent-organic frameworks, and metal oxide frameworks, have greatly enriched the design possibilities of heterostructures with inorganic 2D materials. This review provides a timely summary of the latest advances in synthesis approaches toward advanced organic/inorganic heterostructures, answers the fundamental questions regarding the interfacial interactions in the 2D limit, and further highlights the uses of such organic/inorganic heterostructures in advanced transistors, optoelectronics, neuromorphic, and other multifunctional devices with unique capabilities.

具有广泛结构可调性的二维 (2D) 极限范德华有机/无机异质结构将促进具有定制功能的人造固体的开发。最近在分子单层膜、二维聚合物、共价有机骨架和金属氧化物骨架等几种二维有机材料方面取得的突破极大地丰富了无机二维材料异质结构的设计可能性。这篇综述及时总结了先进有机/无机异质结构合成方法的最新进展，回答了关于二维极限界面相互作用的基本问题，并进一步强调了这种有机/无机异质结构在先进晶体管、光电子学、神经形态，