The self-assembly of discrete molecular entities into functional nanomaterials has become a major research area in the past decades. The library of investigated compounds has diversified significantly, while the field as a whole has matured. The incorporation of metal ions in the molecular design of the (supra-)molecular building blocks greatly expands the potential applications, while also offering a promising approach to control molecular recognition and attractive and/or repulsive intermolecular binding events. Hence, supramolecular polymerization of metal-containing monomers has emerged as a major research focus in the field. In this perspective article, we highlight recent significant advances in supramolecular polymerization of metal-containing monomers and discuss their implications for future research. Additionally, we also outline some major challenges that metallosupramolecular chemists (will) have to face to produce metallosupramolecular polymers (MSPs) with advanced applications and functionalities.

中文翻译：

---

含金属单体超分子聚合的最新进展及未来挑战

离散分子实体自组装成功能纳米材料已成为过去几十年的主要研究领域。研究的化合物库已经显着多样化，而整个领域已经成熟。在（超）分子构建块的分子设计中加入金属离子极大地扩展了潜在应用，同时也提供了一种有前途的方法来控制分子识别和吸引和/或排斥的分子间结合事件。因此，含金属单体的超分子聚合已成为该领域的主要研究热点。在这篇透视文章中，我们重点介绍了含金属单体超分子聚合的最新重大进展，并讨论了它们对未来研究的影响。此外，