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Cellulose Depolymerization with LPMO-inspired Cu Complexes
ChemCatChem ( IF 4.5 ) Pub Date : 2021-09-14 , DOI: 10.1002/cctc.202101169
Ivan Castillo 1 , Andrea P. Torres-Flores 2 , Diego F. Abad-Aguilar 2 , Armando Berlanga-Vázquez 2 , Maylis Orio 3 , Diego Martínez-Otero 4
Affiliation  

Biomimetic chemistry: LPMO-inspired benzimidazole-based copper complexes oxidatively degrade cellulose to cellobiose, aldonic acid and levoglucosan as soluble products in the presence of hydrogen peroxide/triethylamine as oxidant mixture under mild conditions through initially formed cupric hydroperoxo intermediates.
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中文翻译:

用 LPMO 启发的铜配合物解聚纤维素

仿生化学:在温和条件下,在过氧化氢/三乙胺作为氧化剂混合物的存在下,通过最初形成的氢过氧化铜中间体,受 LPMO 启发的基于苯并咪唑的铜配合物将纤维素氧化降解为纤维二糖、醛糖酸和左旋葡聚糖作为可溶性产物。
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更新日期:2021-11-22
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