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Palladium Catalysts with Triglyme-Functionalized NHC Ligands for Suzuki Coupling Reactions in Aqueous Solvent
ChemistrySelect ( IF 2.1 ) Pub Date : 2021-09-13 , DOI: 10.1002/slct.202102092
Qingqing Liu 1, 2 , Jing Zhong 1 , Funing Tian 2 , Qiwei Wang 1 , Yuanhua Wang 3 , Liu Zhong 1 , Qingfei Huang 2
Affiliation  

To perform green chemistry, hydrophilic catalysts with high activity and stability are required. We designed and synthesized a catalyst [Pd(IPr*TEG)(cin)Cl)] from commercially available materials; this catalyst could be used in a wide range of Suzuki coupling reactions in aqueous solvents. The reaction works smoothly under low catalyst loading with a good to excellent yield. It was noted that the catalyst can be recycled, and it performed well in cyclical reactions.

中文翻译:

具有三甘醇二甲醚功能化 NHC 配体的钯催化剂用于水性溶剂中的 Suzuki 偶联反应

为了实现绿色化学,需要具有高活性和稳定性的亲水性催化剂。我们从市售材料中设计并合成了一种催化剂 [Pd(IPr* TEG )(cin)Cl)];该催化剂可广泛用于水性溶剂中的 Suzuki 偶联反应。该反应在低催化剂负载下顺利进行,产率良好至极好。注意到该催化剂可以循环使用,并且在循环反应中表现良好。
更新日期:2021-09-13
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