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Spectroscopic thermodynamic properties of binary liquid mixtures of non-polar and polar solvents (Tetra chloromethane, 2-chloroaniline,2-methylaniline, and 2-methoxyaniline) at various temperatures
Journal of Molecular Liquids ( IF 6 ) Pub Date : 2021-09-13 , DOI: 10.1016/j.molliq.2021.117550
P. Yellareddy 1 , S.K. Fakruddin Babavali 2 , T. Srinivasa Krishna 3 , M. Gowrisankar 4 , Ch.N.S.S. Pavan Kumar 1
Affiliation  

The densities (ρ), viscosities (η) and speeds of sound(u) are reported for binary mixtures of tetrachloromethane with ortho-substituted aniline (2-chloroaniline, 2-methylaniline, and 2-methoxyaniline) over the entire composition range from 298.15 K to 318.15 K and at atmospheric pressure (0.1 MPa). The excess functions and deviation in viscosity are calculated from the densities, speeds of sound and viscosities at experimental temperatures. FT-IR properties have been carried out and analyzed to study the presence of specific interaction such as the formation of hydrogen bonding of the type (N-H·····Cl) between unlike molecules in the binary liquid mixtures. A good agreement is observed among the excess parameters and FT-IR properties.



中文翻译:

非极性和极性溶剂(四氯甲烷、2-氯苯胺、2-甲基苯胺和2-甲氧基苯胺)的二元液体混合物在不同温度下的光谱热力学性质

报告了四氯甲烷与邻位取代苯胺(2-氯苯胺、2-甲基苯胺和 2-甲氧基苯胺)的二元混合物的密度 ( ρ )、粘度 ( η ) 和声速 ( u ) 在 298.15 K 至 318.15 K,在大气压 (0.1 MPa) 下。根据密度、声速和实验温度下的粘度计算超额函数和粘度偏差。FT-IR 特性已被执行和分析,以研究特定相互作用的存在,例如在二元液体混合物中不同分子之间形成 (NH·····Cl) 类型的氢键。在过量参数和 FT-IR 特性之间观察到良好的一致性。

更新日期:2021-09-17
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