We present the synthesis of (tert-butoxy)oligosilanes using [β-(tert-butoxy)disilanyl]lithium, which was prepared by (a) the reduction of (tert-butoxy)chlorodiphenylsilane with lithium and (b) tin-lithium exchange of [(tert-butoxy)diphenylsilyl]stannane with n-BuLi. Functional group transformations of the obtained oligosilanes were successful to form hydro-, fluoro-, and chloro-substituted oligosilanes.

中文翻译：

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使用[β-(烷氧基)二硅烷基]锂合成烷氧基取代的低聚硅烷

我们介绍了使用 [ β -（叔丁氧基）二硅烷基] 锂合成（叔丁氧基）低聚硅烷，锂是通过（a）用锂还原（叔丁氧基）氯二苯基硅烷和（b）锡-锂交换制备的[(叔丁氧基)二苯基甲硅烷基]锡烷与正丁基锂。获得的低聚硅烷的官能团转化成功地形成了氢、氟和氯取代的低聚硅烷。