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MoCS@NSC with interfacial heterojunction nanostructure: A highly selective catalyst for synthesizing methanol from CO2 at low temperature
Journal of Environmental Chemical Engineering ( IF 7.7 ) Pub Date : 2021-09-10 , DOI: 10.1016/j.jece.2021.106354
Han Han 1 , Pingping Cui 1 , Linfei Xiao 1 , Wei Wu 1
Affiliation  

An hybrid Mo2C and MoS2 with an interfacial heterojunction nanostructure confined in N,S- codoped carbon (MoCS@NSC) was prepared by using ionic liquids as all-in-one precursors at the different carbonization temperature. MoCS was highly dispersed in NSC and its average size was 2.5 nm. An interfacial heterojunction nanostructure was formed between the MoS2 (101) and Mo2C (200). Over the MoCS@NSC-800, the MeOH selectivity can reach to 97.3% with only 2.4% and 0.3% selectivity of methane and DME, respectively, at a CO2 conversion of 20.0%, and the STY of methanol was arrived at 0.542 gmethanol gcat−1 h−1. In addition, MoCS@NSC catalyst showed the excellent catalytic performance at 180 °C.



中文翻译:

具有界面异质结纳米结构的 MoCS@NSC:一种用于在低温下从 CO2 合成甲醇的高选择性催化剂

通过使用离子液体作为多合一的前驱体,在不同的碳化温度下制备了界面异质结纳米结构限制在 N,S-共掺杂碳中的混合 Mo 2 C 和 MoS 2 (MoCS@NSC)。MoCS 高度分散在 NSC 中,其平均粒径为 2.5 nm。在MoS 2 (101)和Mo 2 C(200)之间形成界面异质结纳米结构。在 MoCS@NSC-800 上,在 CO 2转化率为 20.0% 的情况下,甲醇的选择性可达到 97.3%,而甲烷和二甲醚的选择性分别仅为 2.4% 和 0.3% ,甲醇的 STY 达到 0.542 g乙醇-1 ħ -1. 此外,MoCS@NSC 催化剂在 180 °C 下表现出优异的催化性能。

更新日期:2021-09-21
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