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Structure, thermal stability and dielectric properties of aluminoborosilicate glasses doped with Pr2O3
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2021-09-12 , DOI: 10.1007/s10854-021-06954-8
Jingang Zhao 1 , Xiaokun Tian 1 , Lulu Zhang 1 , Ya Qu 1 , Chao Wu 1 , Yunlong Yue 1 , Junfeng Kang 1 , Fengyang Zhao 2 , Xianjing Chen 3 , Xunmei Liang 4
Affiliation  

The structure, thermal stability and dielectric properties of aluminoborosilicate glasses with different contents of Pr2O3 were researched by XRD, FT-IR, DSC and electronic impedance analyzer. FT-IR results showed that the addition of Pr2O3 enhanced the degree of polymerization of glass network. The molar volume decreased at first and then increased, which reached the minimum value with the content of Pr2O3 up to 1.5 mol%. With the addition of Pr2O3 the glass transition temperature (Tg) showed an upward trend, while Dietzel's thermal stability (ΔT) and the Saad parameter (S) both increased initially to be followed by a decrease, which indicated that the thermal stability of glass can be improved by doping proper content of Pr2O3. The dielectric constant (εr) and dielectric loss (tanα) both decreased at first then started to go up as the content of Pr2O3 increased. When Pr2O3 content moved up to 0.5 mol% and 1.5 mol%, the εr and tanα reached the minimum values 4.68 and 3.13 × 10–4, respectively.



中文翻译:

掺杂 Pr2O3 的铝硼硅酸盐玻璃的结构、热稳定性和介电性能

采用XRD、FT-IR、DSC和电子阻抗分析仪研究了不同Pr 2 O 3含量的铝硼硅酸盐玻璃的结构、热稳定性和介电性能。FT-IR结果表明Pr 2 O 3 的加入提高了玻璃网络的聚合度。摩尔体积先减小后增大,当Pr 2 O 3含量达到1.5 mol%时达到最小值。随着Pr 2 O 3的加入,玻璃化转变温度(T g)呈上升趋势,而Dietzel 的热稳定性(Δ T)和Saad参数( S )均先增大后减小,表明适当掺杂Pr 2 O 3可以提高玻璃的热稳定性。随着Pr 2 O 3含量的增加,介电常数(ε r)和介电损耗(tanα)均先降低后开始升高。当Pr 2 O 3含量上升到0.5 mol% 和1.5 mol% 时,ε r和tanα 分别达到最小值4.68 和3.13 × 10 –4

更新日期:2021-09-12
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