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Sustainable synthesis of CO2-derived polycarbonates from D-xylose
Polymer Chemistry ( IF 4.6 ) Pub Date : 2021-09-10 , DOI: 10.1039/d1py00784j
David K. Tran 1 , Ahmed Z. Rashad 1 , Donald J. Darensbourg 1 , Karen L. Wooley 1, 2, 3
Affiliation  

Synthetic transformation of D-xylose into a four-membered cyclic ether allows for reactions with carbon dioxide (CO2) leading to linear polycarbonates by either a one-step ring-opening copolymerisation (ROCOP) directly, or by sequential isolation of a preformed six-membered cyclic carbonate followed by ring-opening polymerisation (ROP).

中文翻译:

从 D-木糖可持续合成 CO2 衍生的聚碳酸酯

D-木糖合成转化为四元环醚允许与二氧化碳 (CO 2 )反应,通过一步开环共聚 (ROCOP) 直接或通过顺序分离预先形成的六-元环状碳酸酯,然后进行开环聚合 (ROP)。
更新日期:2021-09-10
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