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Two-dimensional interface engineering of NiS/MoS2/Ti3C2Tx heterostructures for promoting electromagnetic wave absorption capability
Composites Part B: Engineering ( IF 13.1 ) Pub Date : 2021-09-10 , DOI: 10.1016/j.compositesb.2021.109306
Ming Chang 1 , Zirui Jia 1, 2, 3 , Shuangqiao He 1 , Jixi Zhou 1 , Shuo Zhang 1 , Mengli Tian 1 , Bingbing Wang 1 , Guanglei Wu 1
Affiliation  

For the purpose of achieving excellent electromagnetic wave absorption performance, composition control and microstructure design of absorbers are crucial. Ti3C2Tx, transition metal carbides with remarkable conductivity and mechanical properties, are considered as common substrates to construct high-performance absorbers. In order to improve the impedance matching and enrich electromagnetic wave attenuation mechanism of single Ti3C2Tx substrate, transition metal sulfides (MoS2, NiS) with outstanding dielectric properties are introduced to fabricate the novel system of NiS/MoS2/Ti3C2Tx. Notably, this system has a unique multilayer-scale structure that spherical NiS particles are decorated on the multilayered Ti3C2Tx substrate and two-dimensional (2D) MoS2 nanosheets stack on the surface like scales. Under the synergistic effects of intense dielectric loss and multiple reflection, NiS/MoS2/Ti3C2Tx hybrid shows the wide effective absorption bandwidth (EAB) of 5.04 GHz at 2.1 mm and the minimum reflection loss (RLmin) of −58.48 dB at 2.4 mm. This work provides an innovative idea for the research of novel MXene-based absorbers.



中文翻译:

NiS/MoS2/Ti3C2Tx异质结构二维界面工程提高电磁波吸收能力

为了实现优异的电磁波吸收性能,吸收体的成分控制和微观结构设计至关重要。Ti 3 C 2 T x 是具有显着导电性和机械性能的过渡金属碳化物,被认为是构建高性能吸收体的常用基材。为了提高单个Ti 3 C 2 T x衬底的阻抗匹配和丰富电磁波衰减机制,引入具有优异介电性能的过渡金属硫化物(MoS 2,NiS)制备NiS/MoS 2 /Ti新体系3 C 2Ť X。值得注意的是,该系统具有独特的多层级结构,球形 NiS 颗粒装饰在多层 Ti 3 C 2 T x基板上,二维 (2D) MoS 2纳米片堆叠在表面上,如鳞片状。在强介电损耗和多次反射的协同作用下,NiS/MoS 2 /Ti 3 C 2 T x混合体在 2.1 mm 处显示出 5.04 GHz 的宽有效吸收带宽 (EAB) 和 - 的最小反射损耗 (RL min ) 2.4 毫米处为 58.48 分贝。这项工作为新型 MXene 基吸收剂的研究提供了创新思路。

更新日期:2021-09-14
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