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The effect of Zn concentration on the structural and optical properties of Cd1-xZnxS nanostructured thin films
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2021-09-09 , DOI: 10.1007/s10854-021-06980-6
M. Isik 1 , M. Terlemezoglu 2, 3 , S. Isik 2 , K. Erturk 2 , N. M. Gasanly 4
Affiliation  

The structural and optical properties of electrodeposited Cd1-xZnxS nanostructured thin films were investigated in the present paper for compositions of x = 0, 0.03, 0.06 and 0.09. X-ray diffraction patterns of the deposited thin films consisted of diffraction peaks related to cubic crystal lattice. The atomic compositional ratios were determined by performing energy dispersive spectroscopy measurements. Scanning electron microscopy images indicated that deposited thin films have nanostructured forms. Raman spectra of the Cd1-xZnxS thin films exhibited two vibrational modes associated with longitudinal optical mode and its first overtone. Transmission measurements were performed on the deposited thin films to get their band gap energies. It was seen from the analyses of absorption coefficient that band gap energy of Cd1-xZnxS thin films increases almost linearly from 2.40 to 2.51 eV as the composition was increased from x = 0 to x = 0.09.



中文翻译:

Zn浓度对Cd1-xZnxS纳米结构薄膜结构和光学性能的影响

本文研究了电沉积 Cd 1-x Zn x S 纳米结构薄膜的结构和光学特性,其中x  = 0、0.03、0.06 和 0.09 的组成。沉积薄膜的 X 射线衍射图由与立方晶格相关的衍射峰组成。通过进行能量色散光谱测量来确定原子组成比。扫描电子显微镜图像表明沉积的薄膜具有纳米结构形式。Cd 1-x Zn x 的拉曼光谱S 薄膜表现出与纵向光学模式及其第一泛音相关的两种振动模式。对沉积的薄膜进行透射测量以获得它们的带隙能量。从吸收系数的分析中可以看出,随着组成从x  = 0 增加到x  = 0.09 ,Cd 1-x Zn x S 薄膜的带隙能量从 2.40 eV 几乎线性增加到 2.51 eV 。

更新日期:2021-09-10
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