Para-C60(CF2)(CF3)R: a family of chiral electron accepting compounds accessible through a facile one-pot synthesis,European Journal of Organic Chemistry

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Para-C60(CF2)(CF3)R: a family of chiral electron accepting compounds accessible through a facile one-pot synthesis
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-09-09 , DOI: 10.1002/ejoc.202101069
Viktor P. Bogdanov ₁ , Veronika A. Dmitrieva ₁ , Alexey V. Rybalchenko ₁ , Tatiana S. Yankova ₁ , Maria P. Kosaya ₁ , Natalia A. Romanova ₁ , Nikita M. Belov ₁ , Nataliya E. Borisova ₁ , Sergey I. Troyanov ₁ , Alexey A Goryunkov ₂

Affiliation

Efficient one-pot difluoromethylation of C₆₀(CF₃)⁻ leads to the formation of the chiral C₆₀(CF₂)(CF₃)⁻ anion that can be alkylated to produce electron-accepting C₆₀(CF₂)(CF₃)R due to the sp² hybridization of one of the bridgehead atoms of the CF₂ moiety.

中文翻译：

Para-C60(CF2)(CF3)R：可通过简单的一锅法合成获得的一系列手性电子接受化合物

C ₆₀ (CF ₃ ) ^{- 的}高效一锅二氟甲基化导致形成手性 C ₆₀ (CF ₂ )(CF ₃ ) ^-阴离子，该阴离子可以被烷基化以产生接受电子的 C ₆₀ (CF ₂ )(CF ₃ )R 由于CF ₂部分的桥头原子之一的 sp ²杂化。

更新日期：2021-10-01

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