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Sunlight-promoted photodegradation of Congo red by cadmium-sulfide decorated graphene aerogel
Chemosphere ( IF 8.8 ) Pub Date : 2021-09-09 , DOI: 10.1016/j.chemosphere.2021.132225
Jaidev Kaushik 1 , Himanshi 1 , Vishrant Kumar 2 , Kumud Malika Tripathi 3 , Sumit Kumar Sonkar 1
Affiliation  

Herein, a simpler-viable methodology for the surface decoration of pear fruit derived graphene aerogel (GA) via cadmium sulfide (CdS) has been presented. GA can be easily synthesized from bio-mass, which provide an economic advantage. Surface decoration via CdS imparts photocatalytic activities in functionalized graphene aerogels (f-GA). CdS-f-GA is being explored here as a photocatalyst for the degradation of a toxic azo dye named Congo red in the presence of sunlight. The rate and mechanism associated with photodegradation were analyzed by performing kinetics and radical trap-based quenching experiments. Nuclear magnetic resonance and fourier transform infrared spectroscopy analyses of the control and photodegraded products were performed to ensure the degradation of the organic framework of Congo red. Additionally, the real-life applicability of CdS-f-GA was also analyzed by degrading the dye in different types of industrial samples (via the method of external spiking), which can advance its practical relevance.



中文翻译:

硫化镉修饰的石墨烯气凝胶在阳光下光降解刚果红

在此,提出了一种通过硫化镉 (CdS) 对梨果实衍生的石墨烯气凝胶 (GA) 进行表面装饰的更简单可行的方法。GA 可以很容易地从生物质中合成,这提供了经济优势。通过 CdS 进行的表面装饰赋予功能化石墨烯气凝胶 (f-GA) 的光催化活性。这里正在探索 CdS-f-GA 作为一种光催化剂,用于在阳光下降解一种名为刚果红的有毒偶氮染料。通过进行动力学和基于自由基陷阱的淬火实验,分析了与光降解相关的速率和机制。对对照和光降解产物进行核磁共振和傅里叶变换红外光谱分析,以确保刚果红有机骨架的降解。此外,

更新日期:2021-09-20
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