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Two-dimensional Porous Framework Assembled through Hydrogen-bonds and Dipole-dipole Interactions
Chemistry Letters ( IF 1.6 ) Pub Date : 2021-09-09 , DOI: 10.1246/cl.210465
Zhuxi Yang 1 , Ayana Moriyama 2 , Ryusei Oketani 2 , Takayoshi Nakamura 1, 3 , Ichiro Hisaki 2
Affiliation  

We demonstrate that a dipole-dipole interaction of the benzo[c][1,2,5]thiadiazole moieties, directional H-bond formation of carboxy groups, and a rigid molecular skeleton enable to yield a structurally-predictable two-dimensional hydrogen-bonded organic framework BTIA-1 from tetratopic carboxylic acid. Activated form BTIA-1a was revealed to have BET surface area of 237 m2g−1 and show selective adsorption of CO2.

中文翻译:

通过氢键和偶极-偶极相互作用组装的二维多孔框架

我们证明苯并[ c ][1,2,5]噻二唑部分的偶极-偶极相互作用、羧基的定向氢键形成和刚性分子骨架能够产生结构可预测的二维氢-来自四元羧酸的键合有机骨架BTIA-1。显示活化形式BTIA-1a具有237m 2 g -1 的BET表面积并且显示CO 2 的选择性吸附。
更新日期:2021-09-09
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