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Theoretical Study on NHC−Ag(I)/Au(I) Catalyzed Mobius Versus Wagner-Meerwein Rearrangements of 2-Methyl-N-methoxyaniline
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2021-09-09 , DOI: 10.1002/ajoc.202100456
Li Dang 1 , Guanglong Huang 2 , Yu-Qi Fang 2 , Shao-Fei Ni 2 , Ming-De Li 2
Affiliation  

A theoretical investigation on twice consecutive 1,3-methoxy rearrangements of 2-methyl-N-methoxyaniline catalyzed by NHC−Ag(I)/Au(I) catalysis is presented and a double-ortho- and multi-substituted aniline is predicted as major product.
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中文翻译:

NHC−Ag(I)/Au(I)催化Mobius与Wagner-Meerwein重排2-甲基-N-甲氧基苯胺的理论研究

提出了对NHC−Ag(I)/Au(I) 催化下 2-甲基-N-甲氧基苯胺连续两次 1,3-甲氧基重排的理论研究,并预测双邻位和多取代苯胺为主要产品。
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更新日期:2021-11-15
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