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2-Iodosylbenzoic acid activated by trifluoromethanesulfonic anhydride: efficient oxidant and electrophilic reagent for preparation of iodonium salts
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2021-09-02 , DOI: 10.1039/d1nj03787k
Akira Yoshimura 1, 2 , Christopher D. Huss 2 , Akio Saito 3 , Tsugio Kitamura 4 , Viktor V. Zhdankin 2
Affiliation  

2-Iodosylbenzoic acid in the presence of trifluoromethanesulfonic anhydride is an efficient oxidant and electrophilic reagent useful for preparation of the corresponding alkenyl and aryliodonium salts. Compared to the previously reported methods of electrophilic activation of 2-iodosylbenzoic acid, this procedure is compatible with acid-sensitive functional groups, requires mild reaction conditions, and affords products in higher yields.

中文翻译:

三氟甲磺酸酐活化的2-碘代苯甲酸:制备碘鎓盐的高效氧化剂和亲电试剂

在三氟甲磺酸酐存在下的 2-碘代基苯甲酸是一种有效的氧化剂和亲电试剂,可用于制备相应的烯基和芳基碘鎓盐。与之前报道的 2-碘基苯甲酸的亲电活化方法相比,该方法与酸敏感官能团兼容,需要温和的反应条件,并提供更高产率的产品。
更新日期:2021-09-08
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