当前位置: X-MOL 学术Phys. Status Solidi B › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Growth and Helicity of Noncentrosymmetric Cu2OSeO3 Crystals
Physica Status Solidi (B) - Basic Solid State Physics ( IF 1.6 ) Pub Date : 2021-09-07 , DOI: 10.1002/pssb.202100152
Aisha Aqeel 1 , Jan Sahliger 1 , Guowei Li 2 , Jacob Baas 3 , Graeme R. Blake 3 , Thomas. T.M. Palstra 3 , Christian H. Back 1, 4
Affiliation  

Cu 2 OSeO 3 Cu2OSeO3 single crystals are grown with an optimized chemical vapor transport technique using SeCl 4 SeCl4 as a transport agent (TA). The optimized growth method allows to selectively produce large high-quality single crystals. The method is shown to consistently produce Cu 2 OSeO 3 Cu2OSeO3 crystals of maximum size 8 × 7 × 4 mm with a transport duration of around three weeks. It is found that this method, with SeCl 4 SeCl4 as TA, is more efficient and simple compared with the commonly used growth techniques reported in literature with HCl gas as TA. The Cu 2 OSeO 3 Cu2OSeO3 crystals have very high quality and their absolute structures are fully determined by simple single-crystal X-ray diffraction. Enantiomeric crystals with either left- or right-handed chiralities are observed. The magnetization and ferromagnetic resonance data show the same magnetic phase diagram as reported earlier.

中文翻译:

非中心对称 Cu2OSeO3 晶体的生长和螺旋度

2 氧化硅 3 2氧化硅3使用优化的化学气相传输技术生长单晶 氯化钠 4 氯化钠4作为运输代理(TA)。优化的生长方法允许选择性地生产大的高质量单晶。该方法被证明可以始终如一地产生 2 氧化硅 3 2氧化硅3最大尺寸为 8 × 7 × 4 mm 的晶体,运输时间约为三周。发现该方法与 氯化钠 4 氯化钠4作为 TA,与文献中报道的以 HCl 气体作为 TA 的常用生长技术相比,更为有效和简单。这 2 氧化硅 3 2氧化硅3晶体具有非常高的质量,其绝对结构完全由简单的单晶 X 射线衍射确定。观察到具有左手或右手手性的对映体晶体。磁化强度和铁磁共振数据显示与之前报道的相同的磁相图。
更新日期:2021-09-07
down
wechat
bug