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Growth and Helicity of Noncentrosymmetric Cu2OSeO3 Crystals
Physica Status Solidi (B) - Basic Solid State Physics ( IF 1.6 ) Pub Date : 2021-09-07 , DOI: 10.1002/pssb.202100152 Aisha Aqeel 1 , Jan Sahliger 1 , Guowei Li 2 , Jacob Baas 3 , Graeme R. Blake 3 , Thomas. T.M. Palstra 3 , Christian H. Back 1, 4
Cu2OSeO3 single crystals are grown with an optimized chemical vapor transport technique using SeCl4 as a transport agent (TA). The optimized growth method allows to selectively produce large high-quality single crystals. The method is shown to consistently produce Cu2OSeO3 crystals of maximum size 8 × 7 × 4 mm with a transport duration of around three weeks. It is found that this method, with SeCl4 as TA, is more efficient and simple compared with the commonly used growth techniques reported in literature with HCl gas as TA. The Cu2OSeO3 crystals have very high quality and their absolute structures are fully determined by simple single-crystal X-ray diffraction. Enantiomeric crystals with either left- or right-handed chiralities are observed. The magnetization and ferromagnetic resonance data show the same magnetic phase diagram as reported earlier.
中文翻译:
非中心对称 Cu2OSeO3 晶体的生长和螺旋度
铜2氧化硅3 使用优化的化学气相传输技术生长单晶氯化钠4 作为运输代理(TA)。优化的生长方法允许选择性地生产大的高质量单晶。该方法被证明可以始终如一地产生铜2氧化硅3 最大尺寸为 8 × 7 × 4 mm 的晶体,运输时间约为三周。发现该方法与氯化钠4 作为 TA,与文献中报道的以 HCl 气体作为 TA 的常用生长技术相比,更为有效和简单。这铜2氧化硅3 晶体具有非常高的质量,其绝对结构完全由简单的单晶 X 射线衍射确定。观察到具有左手或右手手性的对映体晶体。磁化强度和铁磁共振数据显示与之前报道的相同的磁相图。
更新日期:2021-09-07
Physica Status Solidi (B) - Basic Solid State Physics ( IF 1.6 ) Pub Date : 2021-09-07 , DOI: 10.1002/pssb.202100152 Aisha Aqeel 1 , Jan Sahliger 1 , Guowei Li 2 , Jacob Baas 3 , Graeme R. Blake 3 , Thomas. T.M. Palstra 3 , Christian H. Back 1, 4
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中文翻译:
非中心对称 Cu2OSeO3 晶体的生长和螺旋度