The study of the influence of different substances introduced on the same matrix will provide a good guide for the construction of materials with good properties. A series of transitions/lanthanides metal ions doped or co-doped Al₂O₃ aerogel materials with three-dimensional nano porous structure were fabricated by a simple and facile modified sol-gel method. The effect of different transitions/lanthanides metal ions on the microstructure, textural properties, and luminescence properties of Al₂O₃ aerogels were investigated. By co-doping the Al₂O₃ aerogel matrix with Eu³⁺ and Tb³⁺, we fabricated Al₂O₃ aerogel luminescent materials with tunable color emissions under UV excitation. The characterization results showed that the microscopic morphology of these aerogels induced by transitions/lanthanides metal ions were obviously different. Interestingly, Al₂O₃-Eu/Tb (III) and Al₂O₃-Tb/Ce (III) aerogels exhibited a special flower-like structure. It is hoped that our work will offer some efforts for the preparation of functional materials with excellent properties.

研究不同物质对同一基体的影响，将为构建具有良好性能的材料提供良好的指导。采用简单易行的改性溶胶-凝胶法制备了一系列具有三维纳米多孔结构的过渡/镧系金属离子掺杂或共掺杂的Al ₂ O ₃气凝胶材料。研究了不同过渡/镧系金属离子对Al ₂ O ₃气凝胶的微观结构、织构性能和发光性能的影响。通过用Eu ³⁺和Tb ³⁺共掺杂Al ₂ O ₃气凝胶基质，我们制造了Al ₂ O_{3 种}气凝胶发光材料在紫外线激发下具有可调颜色发射。表征结果表明，过渡/镧系金属离子诱导的这些气凝胶的微观形貌明显不同。有趣的是，Al ₂ O ₃ -Eu/Tb (III) 和Al ₂ O ₃ -Tb/Ce (III) 气凝胶表现出特殊的花状结构。希望我们的工作能为制备具有优异性能的功能材料做出一些努力。