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Multiferroic properties in Sm1-xErxFeO3 ceramics
Journal of Magnetism and Magnetic Materials ( IF 2.7 ) Pub Date : 2021-09-07 , DOI: 10.1016/j.jmmm.2021.168515
Raheleh Tabrizi Dehno , Davoud Sanavi Khoshnoud

The effect of Er3+ substitution on the physical properties of SmFeO3 was studied through magnetic and electrical measurements. The X-ray diffraction patterns of Sm1-xErxFeO3 samples showed that the lattice constants decrease with increasing Er content. As a result, the distortion of Er -doped SmFeO3became significant. The magnetic hysteresis loops of samples indicate that the antiferromagnetic trend increases with Er concentration. The anomaly in Ac susceptibility (χ) and dielectric constant curves for Sm1-xErxFeO3 provided evidence for occurring spin reorientation transition (SRT) in these compounds and are also observed the gradual decrease in SR temperature with increasing Er3+ions. Furthermore, the electrical measurements exhibited a considerable enhancement in the dielectric constant. Sm0.3Er0.7FeO3 is the only compound that presented a colossal dielectric constant (CDC) (103) at room temperature which is attributed to relaxor-ferroelectrics. Likewise, the appearance of magnetic and ferroelectric hysteresis loops indicated the coexistence of magnetism and ferroelectricity.



中文翻译:

Sm1-xErxFeO3 陶瓷的多铁性

的效果 r3+ 物理性质的替代 F电子3通过磁和电测量进行了研究。X射线衍射图谱1——XrXF电子3 样品表明晶格常数随着增加 r内容。结果,畸变r -掺杂 F电子3变得很重要。样品的磁滞回线表明反铁磁趋势随着r专注。Ac 磁化率异常 (χ) 和介电常数曲线 1——XrXF电子3 提供了在这些化合物中发生自旋重定向转变 (SRT) 的证据,并且还观察到随着温度的增加,SR 温度逐渐降低 r3+离子。此外,电测量显示介电常数显着提高。0.3r0.7F电子3是唯一在室温下呈现巨大介电常数 (CDC) (10 3 ) 的化合物,这归因于弛豫铁电体。同样,磁滞回线和铁电磁滞回线的出现表明磁性和铁电性并存。

更新日期:2021-09-27
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