Abstract

Geminal difluoroalkenes are readily available building blocks for the synthesis of a broad spectrum of organofluorine compounds. The review summarizes published data on radical reactions involving geminal difluoroalkenes. These processes include addition of a radical species to a double bond or one-electron reduction of the difluoroalkene fragment. Particular emphasis has been placed on photocatalytic reactions initiated by visible light.

中文翻译：

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Geminal 二氟烯烃的自由基官能化

摘要

Geminal 二氟烯烃是合成广谱有机氟化合物的容易获得的构件。该评论总结了有关涉及孪生二氟烯烃的自由基反应的已发表数据。这些过程包括将自由基物质添加到双键或二氟烯烃片段的单电子还原。特别强调了由可见光引发的光催化反应。