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Detection of New 3,4-Dimethylpyrrole Derivatives upon the Incubation of Exogenous Amines with Extract of Onion (
Heterocycles ( IF 0.6 ) Pub Date : 2021-09-07 , DOI: 10.3987/com-21-14541
Seikou Nakamura , Taichi Yoneda , Shogo Okui , Sayaka Okazaki , Souichi Nakashima , Hisashi Matsuda

Seven new N-substituted 3,4-dimethylpyrroles were obtained in situ through the reaction of an amine ((L)-phenylalanine, (L)-tryptophan, (L)-leucine, (L)-methionine, 1-phenethylamine, aniline or dodecylamine) and a mixture of unstable sulfur-containing compounds derived from the reaction of amino acids in Allium cepa and plant enzyme alliinase. In addition, a plausible reaction mechanism for the synthesis of N-substituted 3,4-dimethylpyrroles was displayed.

中文翻译:

外源胺与洋葱提取物一起孵育时检测新的 3,4-二甲基吡咯衍生物(

通过胺(( L )-苯丙氨酸、( L )-色氨酸、( L )-亮氨酸、( L )-蛋氨酸、1-苯乙胺、苯胺)的反应原位获得7个新的N-取代的3,4-二甲基吡咯或十二胺)和不稳定的含硫化合物的混合物,这些化合物来源于洋葱中的氨基酸和植物酶蒜氨酸酶的反应。此外,还展示了合成N-取代的 3,4-二甲基吡咯的合理反应机制
更新日期:2021-09-07
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