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Magnetic properties and magnetocaloric effect of Tb2Rh3Ge
Journal of Magnetism and Magnetic Materials ( IF 2.7 ) Pub Date : 2021-09-06 , DOI: 10.1016/j.jmmm.2021.168444
Baidyanath Sahu 1 , André M. Strydom 1
Affiliation  

We report the structural, and magnetic properties as well as magnetocaloric effect of a polycrystalline compound of Tb2Rh3Ge. This compound crystallizes with Mg2Ni3Si-type of rhombohedral Laves phases (space group R3m, hR18). The magnetic properties and magnetocaloric effect of Tb2Rh3Ge are explored through dc-magnetization measurements. Temperature dependence of magnetization revealed that the compound exhibits ferromagnetic behavior with TC=56 K. The field dependence of magnetization indicates that Tb2Rh3Ge is a soft ferromagnet. The obtained isothermal magnetic entropy changes (ΔSm) and refrigeration capacity (relative cooling power) for a change of magnetic field 0–9 T are 12.74 J kg−1K−1 and 497(680) J/kg respectively. The Arrott plots and universal curve of normalized ΔSm indicate that this compound undergoes a second order ferromagnetic phase transition.



中文翻译:

Tb2Rh3Ge的磁性和磁热效应

我们报告了多晶化合物的结构和磁性以及磁热效应 结核病23. 该化合物结晶为23- 菱面体 Laves 相的类型(空间群 电阻3, hR18)。磁特性和磁热效应结核病23通过直流磁化测量进行探索。磁化强度的温度依赖性表明该化合物表现出铁磁行为C=56 K. 磁化强度的场相关性表明 结核病23是软铁磁体。得到的等温磁熵变(Δ) 和制冷能力(相对冷却功率)对于 0-9 T 的磁场变化分别为 12.74 J kg -1 K -1和 497(680) J/kg。归一化的阿罗特图和通用曲线Δ 表明该化合物经历了二阶铁磁相变。

更新日期:2021-09-15
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