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Geometrically isomeric [Ir(iqbt)(ppy)(hpa)] complexes with differential molecule orientations for efficient near-infrared (NIR) polymer light-emitting diodes (PLEDs)
Journal of Materials Chemistry C ( IF 6.4 ) Pub Date : 2021-08-23 , DOI: 10.1039/d1tc03203h
Wentao Li 1 , Jiaxiang Liu 1 , Baowen Wang 1 , Siyu Hou 1 , Xingqiang Lü 1 , Guorui Fu 1, 2 , Wai-Yeung Wong 2
Affiliation  

Based on geometrical isomerisation of [Ir(C^N1)(C^N2)(N^O)]-tris-heteroleptic Ir(III)-complexes, the augmented transition dipole transition (TMD) with a preferential horizontal orientation, beneficial for their photo-excited and electroluminescent NIR-phosphorescence, is reported.

中文翻译:

具有不同分子取向的几何异构 [Ir(iqbt)(ppy)(hpa)] 配合物用于高效的近红外 (NIR) 聚合物发光二极管 (PLED)

基于 [Ir(C^N 1 )(C^N 2 )(N^O)]-tris-heteroleptic Ir( III ) -复合物的几何异构化,具有优先水平取向的增强跃迁偶极跃迁 (TMD),据报道,有益于它们的光激发和电致发光 NIR 磷光。
更新日期:2021-09-06
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