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Impact of Surface Defects on LaNiO3 Perovskite Electrocatalysts for the Oxygen Evolution Reaction
Chemistry - A European Journal ( IF 4.3 ) Pub Date : 2021-09-06 , DOI: 10.1002/chem.202102672
Hamidreza Arandiyan 1, 2 , Sajjad S Mofarah 3 , Yuan Wang 2, 4 , Claudio Cazorla 5 , Deshetti Jampaiah 2 , Magnus Garbrecht 6 , Karen Wilson 2 , Adam F Lee 2 , Chuan Zhao 4 , Thomas Maschmeyer 1
Affiliation  

Promoting renewable energy production: LaNiO3 perovskite electrocatalysts have been prepared by a sol-gel protocol. Subsequent calcination at 700 °C yields a macroporous material with modest surface area. Hydrogen reduction induces surface defects, in particular a high concentration of surface oxygen vacancies. The resulting electrocatalyst exhibits a significantly higher current density at lower overpotential, with faster kinetics and superior stability for oxygen evolution for water splitting.
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中文翻译:

表面缺陷对用于放氧反应的 LaNiO3 钙钛矿电催化剂的影响

促进可再生能源生产:LaNiO 3钙钛矿电催化剂已通过溶胶-凝胶协议制备。随后在 700 °C 下煅烧产生具有适度表面积的大孔材料。氢还原引起表面缺陷,特别是高浓度的表面氧空位。所得电催化剂在较低的过电位下表现出明显更高的电流密度,具有更快的动力学和优异的水分解析氧稳定性。
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更新日期:2021-10-19
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